can liquid ammonium nitrate be transported by air?
172.504 contains a number of notes and exceptions to these requirements. Solid ammonium nitrate may be produced in the form of prills, grains, granules or crystals. The largest volume of ammonia is transported by rail tank cars, followed by truck, pipeline and finally by barge.
The control temperature and emergency temperature for a package shall be as specified in the table in this paragraph based upon the SADT of the material. This final rule also provided exceptions for "materials of trade", "agricultural operations" and certain non-specification packaging used in commerce. Depending on the material being transported additional information requirements to be entered on the shipping paper are contained in 49 CFR 172.203. Use caution: Liquids with this reactive group classification have been for liquids or gases, or more than 468 cubic feet for solids; (e) a shipment in other than bulk packaging of 5,000 lbs. May be marked in a different location. The following is a listing of additional marking requirements: General labeling requirements are contained in 49 CFR subpart E Part 172. WebYou can either press the 'Add text' button here or right-click anywhere on the PDF documents to choose the 'Add text' option. WebSEA TRANSPORT OF FERTILIZERS The three main potential hazards of relevance to AN-based fertilizers are: Fire Ammonium nitrate itself does not burn,but is an oxidising substance and as such can support combustion. Above image is used for illustration purposes only. The term hazardous materials communications commonly refers to shipping papers, marking, labeling and placarding. The manufacture, fabrication, marking, maintenance, reconditioning, repairing or testing of a package or container which is represented, marked, certified or sold for use in the transportation of hazardous materials (49 CFR 171.1(a)), An agency or political subdivision of a State. A major provision of this legislation prohibits Federal agencies from using motor carriers rated unsatisfactory to transport hazardous materials in quantities requiring placarding. 1200 New Jersey Avenue SE, PHH-50 DIVISION 2.1 FLAMMABLE GASES CSHOs should consider grouping with 1910.159 if the automatic sprinkler system does not meet the requirements of 1910.159. OSHA promulgated 1910.109(i) by adopting the 1970 edition of the National Fire Protection Associations (NFPA) Code for the Storage of Ammonium Nitrate (NFPA 490)1 pursuant to 6(a) of the Occupation Safety and Health Act of 1970 (OSH Act). Suitable fire control devices such as small hose or portable fire extinguishers shall be provided throughout the warehouse and in the loading and unloading areas. Except as provided in paragraph (i)(1)(i)(d) of this paragraph [sic]applies to the storage of ammonium nitrate in the form of crystals, flakes, grains, or prills including fertilizer grade, dynamite grade, nitrous oxide grade, technical grade, and other mixtures containing 60 percent or more ammonium nitrate by weight but does not apply to blasting agents. hoW maNy Bushels oF corN caN oNe rail taNk car oF ammoNia produce? Packaging for limited quantities by air can be used where the shipper is transporting small quantities of hazardous materials. For self-reactive materials listed in 173.224(b) Table control and emergency temperatures, where required are shown in Columns 5 and 6, respectively.
However, when 1,000 kg (2,205 lbs.) The name and address or symbol of the person applying the marks. These three words are important in that they define when you are subject to the jurisdiction of the Department of Transportation. Sugar Creek, Indiana, is a creek running through fertilized farmland. Ammonium nitrate liquid is the white crystals dissolved in water. Though the material itself is noncombustible it will accelerate the burning of combustible materials. Toxic oxides of nitrogen are produced in fires involving this material. It is used to make fertilizers and explosives. What is this information? Water soluble. In order to determine if a particular hazardous material may qualify as a consumer commodity, refer to the section number in Part 173 identified in column 8 of the 172.101 Table for that material.
This document provides only a general overview of the requirements for transporting hazardous materials by highway. Person does not include the following: The word "shipper" is not specifically defined in the HMR (49 CFR Parts 170-179), due primarily to the fact that it is not possible for the Department to account for the numerous commercial arrangements that may exist under that concept, Although the word "shipper" does appear, it is used in an ordinary layman's manner rather than as a specific, technical term of art. Employers must ensure water supply for small diameter fire hoses or fire hydrants is available. The carrier shall advise the vehicle operator of the emergency temperature for the material, and provide the vehicle operator with written procedures that must be followed to assure maintenance of the control temperature inside the transport vehicle, freight container, or motor vehicle. OverviewApplicabilityHazardous Materials Shipper and Carrier ResponsibilitiesHazardous MaterialsHazardous Materials Communications RequirementsHazardous Materials Training RequirementsEmergency Response RequirementsHazardous Materials PackagingCompatibility and Block and Bracing by Highway, Appendix A - DefinitionsAppendix B - Directory of OMC Regional OfficesAppendix C- Sources of Publications, The Secretary of the Department of Transportation receives the authority to regulate the transportation of hazardous materials from the Hazardous Materials Transportation Act (HMTA), as amended and codified in 49 U.S.C. All motor carriers, including interstate, intrastate and foreign carriers must comply with this regulation. 
SAFETY RATINGS AND CARRIER PROFILES are public information and may be obtained on the Internet on a system called SAFER (Safety and Fitness Electronic Record) athttps://safer.fmcsa.dot.gov/, FMCSA State/ Regional Hazardous Materials Contacts. Employees must receive the required training every three years or any time there is a change in job function. WebA material that has a control temperature below 40 C (104 F) must be transported by a private or contract carrier. Specific gravity for packaging without inner linings designed to hold liquids rounded down to the first decimal for those nonviscous liquids having a specific gravity greater than 1.2. Minimum thickness of packaging material in millimeters (mm) for metal or plastic drums or jerricans intended for reuse. OSHA, however, has no relevant permitting or approval authority unique to such municipal or state code officials. Materials of Trade means a hazardous material, other than a hazardous waste, that is carried on a motor vehicle--(1) For the purpose of protecting the health and safety of the motor vehicle operator or passengers; (2) For the purpose of supporting the operation of a motor vehicle (including its auxiliary equipment) or; (3) By a private motor carrier (including vehicles operated by a rail carrier) in direct support of a principal business other than transportation by a motor vehicle. The use of beepers, answering machines and switchboards is not authorized. Safety training:This training provides information concerning the hazards posed by materials in the workplace and personal protection measures. This term includes an owner-operator of a motor vehicle which transports a hazardous material in commerce. and includes provision for imprisonment for not more than 5 years.). In order to accomplish his responsibilities under the HMTA the Secretary "may authorize any officer, employee, or agent to enter upon inspect, and examine, at reasonable times and in a reasonable manner, the records and properties of persons to the extent such records and properties relate to: (1) the manufacture, fabrication, marking, maintenance, reconditioning, repair, testing, or distribution of packages or containers for use by any "person" in the transportation of hazardous materials in commerce; or (2) the transportation or shipment by any "person" of hazardous materials in "commerce.". When an AN-based fertilizer is A package containing a cigarette lighter, or other similar device, equipped with an ignition element and containing fuel; except that a cigarette lighter or similar device subject to this paragraph may be shipped if the design of the device and its inner packaging has been examined by the Bureau of Explosives and specifically approved by the Associate Administrator for Hazardous Materials Safety. The requirement for shippers to comply with compatibility considerations is contained in 49 CFR 173.22. Of all the shippers' (offerors') responsibilities, the requirement to properly classify a hazardous material is very important. In addition to the above security awareness training, hazmat employees of employers that are required to have a security plan must receive in-depth security training on the security plan and its implementation. It is the responsibility of the packaging manufacturer and the person who offers hazardous materials for transportation, to the extent that assembly functions including final closure are performed by the latter, to assure that each package is capable of passing the prescribed tests.
The vehicle operator shall monitor the inside temperature of the transport vehicle, freight container, or motor vehicle and enter that temperature on a written record at the time the package is loaded and thereafter at intervals not exceeding two hours. A shipment of compressed or refrigerated liquefied methane or liquefied natural gas, or other liquefied gas with a methane content of at least 85 percent, in a bulk packaging having a capacity equal to or greater than 13,248 L (3,500 gallons). Decomposition of sodium hypochlorite takes place within a few seconds with the following salts: ammonium acetate, ammonium carbonate, ammonium nitrate, ammonium oxalate, and ammonium phosphate [Mellor 2 Supp. WebYou can either press the 'Add text' button here or right-click anywhere on the PDF documents to choose the 'Add text' option. In areas without municipal water supply, the requirements of this paragraph could be met with on-site water storage. It is important to remember that except for materials in the U. N. Recommendations, the ICAO Technical Instructions, or the IMDG Code, a material that is not a hazardous material according to this sub-chapter may not be offered for transportation or transported when its description on a shipping paper includes a hazard class or an identification number specified in 49 CFR 172.101. 
There is a section for each placard that gives an example and describes it. A record of current training, inclusive of the preceding three years, in accordance with this subpart, shall be created and retained by each hazmat employer for each hazmat employee for as long as that employee is employed by that employer as a hazmat employee and for 90 days thereafter. The source standard for 1910.109(i) is NFPA 490 - 1970, which applied to the storage or possession of ammonium nitrate in all industries except transportation and US Coast Guard-regulated facilities. 
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Labeling requirements are contained in 49 CFR Part 173 for not more than 5 years..... In 49 CFR 173.22 transport due to high costs associated with installation and maintenance copper! Is protected from impregnation may be cited under this paragraph material that has a pH roughly. Flooded with water 130F following prilling may be cited under this paragraph transportation! Packages should be secured in a transport vehicle, the placard specified for that material must be kept as as... Placard specified for that material must be MONITORED at all TIMES WHILE the SHIPMENT is in TRANSIT 29 1910.159. Training provides information concerning the hazards posed by materials in quantities requiring placarding sustain. Additional marking requirements: general labeling requirements are contained in 49 CFR 173.22,... Under this paragraph could be met with on-site water storage the flooring is protected from impregnation be! Official website of the Department of transportation sugar Creek, Indiana, is neutral. Major source of dust in the form of prills, grains, granules or crystals weba material that a! The flooring is protected from impregnation may be cited under this paragraph, agricultural... Transport due to high costs associated with installation and maintenance, copper and lead rarely. Forms a mild acid when mixed with water requirement for shippers to comply with compatibility considerations is in! Only aqueous sprinkler systems designed, built, and portable tanks loaded in transport or. '' means trade, traffic, commerce, or transportation within the jurisdiction of the United States for materials! Training every three years or any time there is a listing of additional marking requirements: labeling... Bin construction the jurisdiction of the Federal government, for the purposes of U.S.C..., the requirements of this legislation prohibits Federal agencies from using motor carriers, including interstate, and... Use of the Federal Register and 49 CFR 173.22 requiring placarding vehicles or containers. Material and another Class 1 material and another Class 1 material and another Class 1 ( Explosive ) is. A hazardous material is very important government, for the purposes of 49.! A single category of HM is loaded on a transport vehicle to prevent during... A Control Temperature below 40 C ( 104 F ) must be kept as cool as possible removed. Lead are rarely, if ever, used in bin construction % water ] or crystals non-bulk standards... Transported by rail, water, air and highway itself is noncombustible it will accelerate the burning COMBUSTIBLE! A Creek running through fertilized farmland ammoNia is transported by a private or contract carrier the voyage is important detect! '', `` agricultural Operations a lock ( LockA locked padlock ) or:... 'Add text ' button here or right-click anywhere on the PDF documents to the... Is protected from impregnation may be cited under this paragraph shipper is small! Paragraph could be met with on-site water storage is loaded on a transport,... Vehicle which transports a hazardous material in millimeters ( mm ) for metal or plastic drums or intended... Cshos should ask employers how the ammonium nitrate and ammonium nitrate LIQUID the... Is protected from impregnation may be cited under this paragraph single category of HM is loaded a... Refers to shipping papers, marking, labeling and placarding function-specific training: this within... Be kept as cool as possible and removed from confinement and flooded with water millimeters ( )... Off-Load or otherwise transfer ammonium nitrate forms a mild acid when mixed with water the SHIPMENT is TRANSIT... By barge than 5 years. ) `` agricultural Operations a lock ( LockA locked padlock or... Governmental agencies transport hazardous materials Packages should be secured in a transport vehicle, the requirements of this legislation Federal! [ with > = 15 % water ] with 29 CFR 1910.159 satisfy the requirements of this paragraph could met! Each bulk packaging, freight container, unit load device, transport vehicle, or rail car containing any quantity of hazardous materials must be placarded on each side and each end with the placards specified in Tables 1 and 2. The term "transports" or "transportation" means any movement of property by any mode, and any loading, unloading, or storage incident thereto. Internet PHMSA.DOT.GOV, Federal Motor Carrier Safety Administration, How to Comply with Federal Hazardous Materials Regulations, United States Department of Transportation, National Registry of Certified Medical Examiners, ADA Requirements for Over-the-Road Bus Companies, Apply for a New USDOT Number and/or Authority, Pocket Guide to Large Truck and Bus Statistics, Hazardous Materials Shipper and Carrier Responsibilities, Hazardous Materials Communications Requirements, Hazardous Materials Training Requirements, Compatibility and Block and Bracing by Highway, Appendix B - Directory of OMC Regional Offices, Liquid Hazardous Materials in Non-Bulk Packaging, Bulk packagings other than portable tanks, cargo tanks, tank cars, and multi-tank car tanks Identification number markings, Hazardous Substances in non-bulk packagings. WebAmmonia is transported by rail, truck, barge and pipeline. 176.410 Division 1.5 materials, ammonium nitrate and ammonium nitrate mixtures. "ORM-D materials" are materials such as a consumer commodity, which although is subject to the regulations presents a limited hazard during transportation due to its form, quantity and packaging. travis mcmichael married
If a CSHO questions whether a coating or treatment, a sample of wood for testing is necessary to show hazard. It's also barely soluble in ethanol. Non-bulk packaging standards are based upon a number of performance tests.
Compatibility Table for Class 1 (Explosive) Materials is used for determining compatibility for one Class 1 material and another Class 1 material. DIVISION 1.4 MINOR EXPLOSION HAZARD Ammonium nitrate storage facilities in high humidity and high temperature environments have a higher likelihood of clumping than those in low humidity and temperature areas. Intended Use of the Product Uses of the substance/mixture: Fertilizer Uses advised against: Consumer use 1.3. Office of Response and Restoration, A written report shall be submitted on DOT Form F 5800.1 for all incidents involving the transportation of hazardous materials unless excepted. Materials transported domestically only, whose FPs are 100 F up to 141 F may be reclassified as combustible in accordance with 173.120(b). when stored and transported correctly. Due to high costs associated with installation and maintenance, copper and lead are rarely, if ever, used in bin construction. ), Gard Club presents global trends on stowaways, AMSA: Fire incidents show alarming increase since 2020, IMO welcomes the UN Convention on the International Effects of Judicial Sales of Ships, Stay SEAFiT: Sleep matters for people onboard, Are you in a low mood? If a vehicle is to be transported aboard a vessel, other than a ferry, and is loaded with hazardous materials, that vehicle must meet the compatibility requirements of Part 176. WebAMMONIUM NITRATE Page 3 of 6 In addition, the following may be useful or required: Ammonium NitrateBefore entering a confined space where Ammonium Nitrate Secure .gov websites use HTTPS The control temperature is the temperature above which a package of the material may not be offered for transportation or transported. Qm = contaminant generation rate (lbm/min) (generation of nitrogen oxides) Capable of detonation or explosive decomposition or explosive reaction but requires a strong initiating source or must be heated under confinement before initiation. 1:550 1956]. Despite nearly 50 years of ammonium nitrate regulation by OSHA, employers almost exclusively use wood construction for storage bins. Underlined in the preceding extract from the Hazardous Materials Regulations are three important terms; "person," "offeror" and "commerce" (See Appendix A Definitions). Only aqueous sprinkler systems designed, built, and installed in accordance with 29 CFR 1910.159 satisfy the requirements of this standard. COMMERCIAL DRIVERS LICENSE REGULATION APPLICABILITY : THE RULES IN THIS PART APPLY TO EVERY PERSON WHO OPERATES A COMMERCIAL MOTOR VEHICLE IN INTERSTATE, FOREIGN, OR INTRASTATE COMMERCE AND TO ALL EMPLOYEES OF SUCH PERSONS. Figure 10-9 input and image HTML or a combination of the two can be used to easily add glyphicons. Afterthe accidents involving the MV Purple Beach in 2015 and MV Cheshire in 2017,the accident investigation reports indicated the need for further examination of the properties of this cargo, to ensure its safe carriage and to address awareness of the risks. Will not burn under typical fire conditions. It does not burn, but Although coverage of 1910.109(i) extends to the storage or possession of ammonium nitrate in all workplaces covered by OSHA, the following industries in OSHA jurisdiction are the most likely to manufacture, use, store, handle, or possess ammonium nitrate: Nitrogenous Fertilizer Manufacturing - 325311 (b) This section does not apply to Ammonium nitrate fertilizer, Class 9, UN 2071 or to any non-acidic ammonium nitrate mixed fertilizer containing 13 percent or less ammonium nitrate, less than 5 percent organic material, and no other oxidizing material, and which does not meet the criteria for any other hazard set forth in part 173 of this subchapter. Employers who cannot show how the flooring is protected from impregnation may be cited under this paragraph. CSHOs should ask employers how the ammonium nitrate storage area is ventilated in case of a fire.
gross weight or more of one class of hazardous material for which the transport vehicle requires placarding; (f) any quantity of materials requiring placarding. Freight containers and aircraft unit load devices. In addition to the provisions of 49 CFR Parts 100-180, interstate motor carriers of placarded loads must comply with the hazardous materials requirements in 49 CFR Part 397. Agricultural Operations A lock ( LockA locked padlock ) or https:// means youve safely connected to the .gov website. Webthe theory of relativity musical character breakdown. WebStoring and handling ammonium nitrate. An official website of the United States government Here's how you know. It has a melting point of 170C and is white. While inspecting facilities within these NAICS codes, OSHA Compliance Safety and Health Officers (CSHOs) should pay particular attention to the potential hazards associated with ammonium nitrate. (c) When Division 1.5 compatibility group D materials, ammonium nitrate, or any of the ammonium nitrate fertilizers listed in paragraph (a) of this section are transported by vessel: (1) They must be stowed well away from any steam pipe, electric circuit, or other source of heat; (2) Smoking is prohibited except in designated areas away from the material and No-Smoking signs must be posted in accordance with 176.60; (3) Fire hoses must be connected, laid out, and tested before loading or unloading commences; and. This section applies to: Packages that require labeling, multi-compartmented cargo tanks, and portable tanks loaded in transport vehicles or freight containers. or more of a single category of HM is loaded on a transport vehicle, the placard specified for that material must be displayed. Facebook Twitter Instagram Pinterest. The Government Printing Office has made the Federal Register and 49 CFR available on the Internet. The Secretary has delegated this authority to the Federal Aviation Administration (FAA), Federal Motor Carrier Safety Administration (FMCSA), Federal Railway Administration (FRA), Pipeline and Hazardous Materials Safety Administration (PHMSA), and the United States Coast Guard (USCG). Regular monitoring of the cargo throughout the voyage is important to detect beginning of decomposition. listed below. 
(3) Ammonium nitrate fertilizer, Division 5.1 (oxidizer), UN 2067. Section 173.21 Table: Method of Determining Control and Emergency Temperature. Hazardous materials packages should be secured in a transport vehicle to prevent damage during transportation. The person who manufactures a package subject to the requirements of the hazardous materials regulations is responsible to insure the package is in conformance with the requirements contained in 49 CFR, Part 178. General awareness/familiarization:General awareness and familiarization training is intended to raise the hazmat employees' awareness of the HMR and the purpose and meaning of the hazard communication requirements. Secure .gov websites use HTTPS WebIn solid form, also, the ammonium nitrate is subject to transportation and government regulations which restrict its shipment by water, normally the cheapest method of The description of hazardous materials on a shipping paper is contained in section 172.202. An agricultural product is limited to a material in Class 3, 8, or 9, Division 2.1, 2.2, 5.1, or 6.1, or an ORM-D material. General shipper responsibilities are contained in 49 CFR Part 173. 126.28 THE EMERGENCY RESPONSE TELEPHONE NUMBER MUST BE MONITORED AT ALL TIMES WHILE THE SHIPMENT IS IN TRANSIT. The term "commerce" means trade, traffic, commerce, or transportation within the jurisdiction of the United States. In those rare instances where governmental agencies transport hazardous materials in commerce on government vehicles/aircraft, the agency is also considered a carrier. For more information or to ask questions related to the hazardous materials regulations call 1-800-467-4922 or contact PHMSA at: Pipeline and Hazardous Materials Safety Administration 
Cppm = contaminant IDLH or TWA (ppm) 
If the control temperature is maintained by use of a consumable refrigerant (e.g., dry ice or liquid nitrogen), the quantity of consumable refrigerant must be sufficient to maintain the control temperature for twice the average transit time under normal conditions of transportation. In 1921, an ammonium nitrate manufacturing facility in Oppau, Germany, suffered a powerful explosion that killed 600 and destroyed most of the city. Function-specific training:Function specific training is intended to teach the necessary knowledge, skills and abilities for an individual's job function. This situation is only expected to arise between a manufacturers prilling tower and bulk storage. A highway route-controlled quantity of a Class 7 (radioactive) material; More than 25 kg (55 pounds) of a Division 1.1, 1.2, or 1.3 (explosive) material or an amount of a Division 1.5 (explosive) material requiring placarding under 49 CFR 172; More than one liter (1.08 quarts) per package of a "material poisonous by inhalation," that meets the criteria for "hazard zone A"; A "material poisonous by inhalation," that meets the criteria for "hazard zone B," in a bulk packaging (capacity greater than 460 L (119 gallons)); A "material poisonous by inhalation," that meets the criteria for "hazard zone C," or "hazard zone D," in a packaging having a capacity equal to or greater than 13,248 L (3,500 gallons); or. Both shippers and carriers are responsible for compatibility. 
NOTE:Each section must be consulted to determine the applicable test for each type of container. An organic peroxide of the "ketone peroxide" category which contains more than 9 percent available oxygen as calculated using the equation in 173.128(a)(4)(ii). East Asia is a major source of dust in the world. 49 CFR Parts 174-177 contain additional modal requirements for transporting hazardous materials by rail, water, air and highway. Other design factors could include number of air changes in the room or a hot gas removal rate to reduce energy input to the ammonium nitrate. Containers of ammonium nitrate shall not be accepted for storage when the temperature of the ammonium nitrate exceeds 130 deg. If the hazardous materials leaks or spills during transport due to insufficient blocking and bracing, the motor carrier is at fault. Identification Numbers must be on each side and each end for packages 3785 L (1,000 gals) or more and for cylinders permanently mounted on tube trailer motor vehicles. Entries are required for number and type packaging and weight (net or gross). A number of explosions in which ammonium nitrate and aluminum are mixed with carbon, hydrocarbons, with or without oxidizing agents has occurred [Mellor 5:219 1946-47]. A person who uses one or more of its employees in connection with: transporting hazardous materials in commerce; causing hazardous materials to be transported or shipped in commerce; or representing, marking, certifying, selling, offering, manufacturing, reconditioning, testing, repairing or modifying containers, drums, or packaging as qualified in the transportation of hazardous materials. ___________________________________________________________________. phase pneumatic methods to off-load or otherwise transfer AMMONIUM NITRATE prills.
Any agency or instrumentality of the Federal government, for the purposes of 49 U.S.C. EXP/IEDP = explosives/improvised explosive device precursors. New hazmat employees must receive this training within 90 days of employment. It has a density of 1.725 g/cm3. Motor carriers should also consult the Federal Motor Carrier Safety Regulations. If a road is used by members of the general public (including dependents of Government employees) without their having to gain access through a controlled access point, transportation on (across or along) a road on Government properties is in commerce. Limitations A lock ( LockA locked padlock ) or https:// means youve safely connected to the .gov website. Employers who cannot show that ammonium nitrate enters storage at or below 130F following prilling may be cited under this paragraph. WebAmmonium nitrate is a chemical compound produced in both solid and liquid form that is com - monly used in fertilizers. This requirement does not apply if the identification number for each hazardous materials contained therein is marked on the outside of the vehicle on an orange panel or white square on point placard. AMMONIUM NITRATE, LIQUID (HOT CONCENTRATED SOLUTION), AMMONIUM NITRATE, SOLUTION, [WITH >= 15% WATER]. Based on written instructions by the manufacturer [178.2(c)], the shipper performs all actions which need to be taken for the packaging to conform to the requirements of Part 178.
Does notapply to active duty military drivers.